Brönsted acidic ionic liquid ([Hmim][HSO4]) as a green, efficient and reusable catalyst for the tetrahydropyranylation of alcohols

نویسندگان

  • Abdol Hajipour Pharmaceutical Research Laboratory, College of Chemistry, Isfahan University of Technology, Isfahan 84156, IRAN Department of Pharmacology, University of Wisconsin Medical School, 1300 University Avenue, Madison, WI, USA 53706-1532
  • Fatemeh Rafiee Pharmaceutical Research Laboratory, College of Chemistry, Isfahan University of Technology, Isfahan 84156, IRAN
چکیده مقاله:

A simple and mild method for tetrahydropyranylation of alcohols is reported at room temperature using a catalytic amount of 3-methylimidazolinium hydrogensulfate([Hmim]HSO4) as a green, efficient and reusable catalyst. Using solvent-free conditions, non-toxic and inexpensive materials, modest and clean work-up, short reaction times and high yields of the products are the advantages of this method.

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منابع مشابه

brönsted acidic ionic liquid ([hmim][hso4]) as a green, efficient and reusable catalyst for the tetrahydropyranylation of alcohols

a simple and mild method for tetrahydropyranylation of alcohols is reported at room temperature using a catalytic amount of 3-methylimidazolinium hydrogensulfate([hmim]hso4) as a green, efficient and reusable catalyst. using solvent-free conditions, non-toxic and inexpensive materials, modest and clean work-up, short reaction times and high yields of the products are the advantages of this method.

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Mild and efficient solvent-free tetrahydropyranylation (THP) of alcohols catalyzed by reusable acidic ionic liquid [Et3N(CH2)4SO3H][OTs]

A variety of alcohols readily add to 3,4-dihydro-2H-pyran under solvent free conditions in the presence of catalytic amount of acidic ionic liquid [Et3N(CH2)4SO3H][OTs] to afford the corresponding tetrahydropyranyl ethers in good to excellent yields at room temperature. The use of this procedure allows easy separation of the desired products ...

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Mild and efficient solvent-free tetrahydropyranylation (THP) of alcohols catalyzed by reusable acidic ionic liquid [Et3N(CH2)4SO3H][OTs]

A variety of alcohols readily add to 3,4-dihydro-2H-pyran under solvent free conditions in the presence of catalytic amount of acidic ionic liquid [Et3N(CH2)4SO3H][OTs] to afford the corresponding tetrahydropyranyl ethers in good to excellent yields at room temperature. The use of this procedure allows easy separation of the desired products ...

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mild and efficient solvent-free tetrahydropyranylation (thp) of alcohols catalyzed by reusable acidic ionic liquid [et3n(ch2)4so3h][ots]

a variety of alcohols readily add to 3,4-dihydro-2h-pyran under solvent free conditions in the presence of catalytic amount of acidic ionic liquid [et3n(ch2)4so3h][ots] to afford the corresponding tetrahydropyranyl ethers in good to excellent yields at room temperature. the use of this procedure allows easy separation of the desired products from ionic liquid and recycling the ionic liquid. som...

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Brønsted Acidic Ionic Liquid: An Efficient and Reusable Catalyst for the Multi-Component Synthesis of Dihydropyrimidinones under Solvent-Free Conditions

An efficient and convenient procedure for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones and thiones by condensation of 1,3-dicarbonyl compounds, Aromatic and aliphatic aldehydes, and urea or thiourea in the presence of catalytic amount of Brønsted acidic ionic liquid 3-methyl-1-sulfonic acid imidazolium chloride {[Msim]Cl} under thermal solvent-free conditions reacted easily to afford the co...

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عنوان ژورنال

دوره 2  شماره 1

صفحات  23- 26

تاریخ انتشار 2012-01-01

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